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Home » INMA researchers develop a revolutionary 4D printing technology using liquid crystal emulsions

INMA researchers develop a revolutionary 4D printing technology using liquid crystal emulsions

by INMAweb
14/12/2024
in Featured
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Investigadores del INMA desarrollan una revolucionaria tecnología de impresión 4D con emulsiones cristal líquido
INMA researchers develop innovative 4D printing technology with liquid crystal emulsions
A breakthrough in smart materials: shape memory, photonic properties and adjustable porosity
A team of researchers from the INMA’s Liquid Crystals and Polymers Group (https://liquidcrystals.unizar.es/) has taken a step forward in 4D printing by developing a technology that uses liquid crystal emulsions as a base material for the manufacture of complex structures with unique functional properties. This work, the result of a collaboration with the University of Heidelberg (Germany), has been published in the prestigious journal Angewandte Chemie, which has highlighted it as a Hot Paper.
The Aragon Nanoscience and Materials Institute (INMA) is a joint institute between CSIC and UNIZAR
This breakthrough combines 3D printing by Digital Light Processing (DLP) with liquid crystal emulsions, allowing the functional properties of liquid crystals to be preserved in printed objects. The resulting structures have shape memory, respond to thermal and light stimuli, and have adjustable intrinsic porosity, as well as the ability to incorporate photonic properties, making them versatile and highly functional materials.
The impact of this technology is broad, with potential applications in areas such as adaptive optics, soft robotics, photonics and biomedicine. This breakthrough also opens up new opportunities for the design of smart materials with customised functionalities.

Read more about this work in our recent publication:

4D printing of liquid cristal emulsions for smart structures with multiple functionalities

Dr. Alberto Concellón, Philipp Mainik, Clara Vázquez-Martel, Cristina Álvarez-Solana, Prof. Dr. Eva Blasco

Angew. Chem. Int. Ed. 2024, e202421162

DOI: 10.1002/anie.202421162

Abstract: 3D printing, and more recently 4D printing, has emerged as a transformative technology for fabricating structures with complex geometries and responsive properties. However, employing functional colloidal solutions as inks for printing remains unexplored. In this work, we present a novel and versatile 4D printing approach for fabricating functional and complex-shaped objects using polymerizable liquid crystal (LC) emulsion droplets. Leveraging a digital light processing (DLP) 3D printing technique, we achieve rapid production of intricate 3D geometries with high resolution. The printed structures retain the LC ordering from the precursor droplets, imparting the final objects with shape memory properties, including shape fixation and recovery upon heating or light exposure. Light-responsive behavior is introduced post-printing by embedding an azo dye into the 3D structures. Additionally, we explore the potential to create intrinsically porous 3D structures by selectively removing non-reactive components from the printed geometries, adding an extra level of functionality to the printed objects. Furthermore, we incorporate chiral nematic LCs into the emulsion droplets, producing 3D objects with tunable reflective properties. To our knowledge, this is the first example of DLP 3D printing with emulsions, offering an effective and versatile pathway for developing 4D-printed materials with potential applications in optics, robotics, microfluidics, and biomedicine.

 

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    • THE INSTITUTE
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